Примеры использования Transition state на Английском языке и их переводы на Русский язык
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This newly designed compound is called a transition state analogue TSA.
Transition state in enzymatic reactions Enzymes are catalysts for living organisms.
The dissociation of the leaving group is the first transition state in a SN1 reaction.
Therefore, the transition state will be more geometrically similar to the reactants than to the products.
Hammond's postulate can be used to examine the structure of the transition states of a SN1 reaction.
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The transition state TS is depicted as a 5-membered ring with partial covalent or double bonding.
In contrast, however, in an endothermic reaction the transition state is closer in energy to the products than to the reactants.
Eyring used potential energy surfaces to calculate reaction rate constants in the transition state theory in 1935.
What is the transition state or reactive intermediate of the above amide bond hydrolysis?
He manages to harmoniously merge the specificity and generalization,the real momentary beauty of nature and its transition state.
For example, in an exothermic reaction the transition state is closer in energy to the reactants than to the products.
At the international level, it was committed to the empowerment of women,particularly in post-conflict and transition States.
It is shown that the geometric structure of the transition state is not intermediate between the initial and final states of the system.
This early model explains enzyme specificity, butfails to explain the stabilization of the transition state that enzymes achieve.
From time to time this transition state has been taught to mortals, and the concept, in distorted form, has found a place in present-day religions.
Hoffmann's research and interests have been in the electronic structure of stable and unstable molecules,and in the study of transition states in reactions.
The postulate states that the structure of a transition state resembles that of the species nearest to it in free energy.
Two successful drugs,saquinavir and amprenavir, contain the structural unit shown below which mimics the transition state within the enzyme.
After the transition state, the A-B bond length continues to decrease, so that much of the liberated reaction energy is converted into vibrational energy of the A-B bond.
Case(c) depicts the potential diagram for an endothermic reaction,in which, according to the postulate, the transition state should more closely resemble that of the intermediate or the product.
Article 113 of the decree-law of transition states that justice shall be rendered by the courts and tribunals throughout the territory of the Republic in the name of the Burundian people.
In contrast the PES for the reaction H+ Cl2→ HCl+ Cl is repulsive(or late-downhill) because R*HCl<R*ClCl and the transition state is reached when the products are separating.
Several countries in transition stated that allowing foreigners to acquire land without restrictions would result in considerable internal economic and social problems.
For exothermic reactions, a PES is classified as attractive(or early-downhill) if R*AB>R*BC, so that the transition state is reached while the reactants are approaching each other.
Representatives from the countries in transition stated that their countries' financial difficulties would limit their ability to attend meetings under the Convention.
There is support for this reaction mechanism:the reaction proceeds in relatively non-polar solvents(in line with transition state) and the reaction kinetics depend on all three reactants.
If two states, as,for example, a transition state and an unstable intermediate, occur consecutively during a reaction process and have nearly the same energy content, their interconversion will involve only a small reorganization of the molecular structures.
For a reaction of type A+ B-C→ A-B+ C, the bond length extension for the newly formed A-B bond is definedas R*AB RAB- R0AB, where RAB is the A-B bond length in the transition state and R0AB in the product molecule.
These parameters, also,determine the angular speed of rotating Vortex Layer(VL) and transition state from the Irrotational Vortex(IRV), when angular speed of the VL is proportional to the radius, to the Rotational Vortex, when the angular speed of the VL is the same and VL looks like a monolithic Vortex cavity.
The requests by Governments for these activities continue to rise because of the growing awareness of the work of UNCITRAL, entry into effect ofits various legal texts, particularly urgent need for modernizing trade laws in developing and transition States;